Fragrances 101
What you need to know about quats
By Bernard Mitzner
Quats have been used in disinfectants
and germicides for more than 25 years. Many companies have used quats as room
sprays to eliminate odors. Their common activity on germs as well as odors is to
destroy them. Quats, which are quaternary ammonium compounds, simply destroy
organic matter.
Quats are used in the automobile industry due to their ability
to aid in the drying of cars after washing with soap containing quats. Quats also give finishes a water-beading effect.
Many of the products that utilize quats also contain
fragrances. Quats destroy fragrances. As a result, some companies offer
lines of quat-stable fragrances.
Unfortunately, many companies using quats are simply not aware
of the adverse effect quats may have on many fragrances.
Regretably, some of the manufacturers of quats do not always
inform their customers that quats have an adverse effect on fragrances. As a result, the customer is not being assisted by the quat
company.
From my discussion with the president of one of the giants,
these companies don’t like to advise their customers of the adverse effects
quats may have on the fragrances they use in their formulations. This stance is
truly regrettable.
I did extensive research on the destruction of fragrances by
quats 25 years ago. I recently repeated this work.
The test
A large number of materials
used in fragrances were chosen materials that consist of both chemicals and
natural oils. Three classes were chosen: aldehydes, alcohols and esters.
Mixtures were reported at various concentrations, but the most striking results
were obtained from fragrances at a concentration of 2 percent and with a
concentration of quats at 10 percent in ethyl alcohol. A temperature of 140
degrees was chosen due to the fact that most warehouses maintain this
temperature during the summer months. The experiment was carried out for 90
days. A gas chromatograph was used to monitor the materials of interest.
The results
Breakdown was very
obvious for essential oils containing aldehydes, such as lemon that contains
citral a alha beta unsaturated aldehyde. Changes were observed for the other
aldehydes. Alcohols were destroyed to a lesser degree, and esters were least
affected.
Aldehydes are a very essential ingredient in many fragrances. Quats break down aldehydes. It is clear that the fragrance
company has to substitute ingredients for the aldehydes. The action of quats in a soap, for example, is insidious
because it does not happen immediately. Therefore, the user is not aware of the
quat having an adverse effect. The reaction is slow and it takes considerable
time for the effect of the destruction to be noted, and it is usually while the
product is in storage. It is therefore essential for the manufacturer to tell
the fragrance company that they are using a quat and at what concentration.
The company using a fragrance for evaluation must test the
fragrance at a temperature of at least 140 degrees and for at least a month. It
must contain at least twice the amount of quat normally used, and you must
compare it with the product that only contains the fragrance and no quat.
Many unsuspecting manufacturers make the product using a quat
and smell it for a day or so and do not see any adverse effects. They therefore
purchase the perfume, use it and then get complaints from customers who indicate
products in storage for several months have lost fragrance.
Finally, it is essential to inform the fragrance company that
you are using a quat and depending on the concentration used, the fragrance
company can suggest a quatstable fragrance.
Bernard Mitzner is the President of Value Fragrances &
Flavors in Goshen, NY.
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